What each mode does
Screen brightens, so the light parts of both pictures show through, which gives the classic double exposure look. Multiply darkens and suits textures such as paper or fabric. Overlay and Soft light add the top picture's contrast and color, Difference produces strong, inverted-looking colors, and Normal simply lays one picture over the other at the opacity you choose.
You do not need to remember any of this. The tiles show each mode on your actual photos, so you can choose by eye.